Chapter Five · Carboxylic acid: practice questions
Chapter Five · Organic chemistry · Chemistry. These are 10 questions from the Magmo3 bank on this lesson, from easy to hard. Solve each one, then open "Show answer and explanation". Magmo3 has 40 questions on this lesson, each with an explanation.
Explanation: Acidity decreases in the order carboxylic acid (ethanoic) > phenol > water > alcohol (ethanol).
Question 5Medium
Why do carboxylic acids have higher boiling points than alcohols of similar molecular mass?
AThey form more complex branched chains.
BThe carboxylic group is more electronegative than the hydroxyl group.
CThey have higher molecular weights due to the carbonyl group.
DEach acid molecule is linked to another by two hydrogen bonds.
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Correct answer: (D) Each acid molecule is linked to another by two hydrogen bonds.
Explanation: The textbook states that carboxylic acids have higher boiling points because each acid molecule is linked to another by two hydrogen bonds, forming association.
Question 6Medium
The carboxyl group (-COOH) of a carboxylic acid can be regarded as a combination of which two groups on the same carbon atom?
AA carboxyl group and a carbonyl group
BA carbonyl group and a hydroxyl group
CA carbonyl group and a carbonyl group
DA hydroxyl group and a hydroxyl group
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Correct answer: (B) A carbonyl group and a hydroxyl group
Explanation: The carboxyl group consists of a carbonyl group (C=O) and a hydroxyl group (-OH) attached to the same carbon atom.
Question 7Medium
Which of the following compounds contains a carbonyl group bound directly to a sodium oxygen ionic bond (salt)?
ACH₃-C(=O)-O-CH₃
BCH₃-C(=O)-O-Na⁺
CCH₃-C(=O)-OH
DCH₃-C(=O)-CH₃
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Correct answer: (B) CH₃-C(=O)-O-Na⁺
Explanation: Structure (c) is CH₃-C(=O)-O⁻Na⁺, which is sodium acetate.
Question 8Hard
Which of the following pairs correctly links a complex chemical with its chemical name/category?
ATNT - Polyvinyl chloride
B(COO)2Ca - Calcium salt of a carboxylic acid
CVitamin C - An aliphatic ester polymer
DTeflon - An aromatic nitro compound
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Correct answer: (B) (COO)2Ca - Calcium salt of a carboxylic acid
Explanation: (COO)2Ca is calcium oxalate, representing a salt of a carboxylic acid as deduced from the context of organic acid derivatives.
Question 9Hard
Which chemical transformation represents the exact reverse (opposite) of reducing acetic acid with hydrogen in the presence of copper chromate at 200°C?
AOxidation of ethanol to acetic acid
BCatalytic hydration of acetylene
COxidation of toluene by atmospheric air at 400°C in the presence of V2O5
DReaction of acetic acid with sodium bicarbonate
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Correct answer: (A) Oxidation of ethanol to acetic acid
Explanation: Carboxylic acids are reduced by hydrogen in the presence of CuCrO4 at 200°C to form ethanol, and notes that 'This reaction is opposite to that of oxidation of alcohols to acids.'.
Question 10Hard
Based on the descriptions of organic acids in our life, what is the precise chemical justification for using sodium benzoate (at 0.1%) and citric acid in foods?
ASodium benzoate prevents the growth of fungi on foods, while citric acid prevents the growth of bacteria in foods because it decreases their pH.
BSodium benzoate decreases the pH to kill bacteria, while citric acid prevents the growth of fungi on frozen fruits.
CBoth compounds act exclusively as artificial sweeteners and flavour enhancers for fruits.
DBoth compounds are used to increase the molecular mass and boiling point of liquid foods.
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Correct answer: (A) Sodium benzoate prevents the growth of fungi on foods, while citric acid prevents the growth of bacteria in foods because it decreases their pH.
Explanation: Sodium benzoate 0.1% is used as foods preservating substance, because it prevents the growth of fungi on foods' and regarding citric acid: 'It prevents the growth of bacteria in foods because it decreases their (pH).